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Margetić D., Štrukil V. Mechanochemical Organic Synthesis

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Margetić D., Štrukil V. Mechanochemical Organic Synthesis
Elsevier Inc., 2016. — 375 p. — ISBN: 978-0-12-802184-2
Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency.
The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area.
Contents
Practical Considerations in Mechanochemical Organic Synthesis
A Historical Perspective
Modern Laboratory Instrumentation for Mechanosynthesis
Contamination From Wear in Organic Mechanosynthesis
Analysis and Monitoring of Mechanochemical Reactions
Carbon–Carbon Bond- Forming Reactions
Heck Coupling
Suzuki Coupling
Sonogashira Coupling
Glaser Coupling
Michael Reaction
Aldol Condensation
Morita–Baylis–Hillman Reaction
Knoevenagel Condensation
Barbier Allylation
Gewald Reaction
Pinacol Reaction
Grignard and McMurry Reactions
Grignard–Zerewitinoff-Like Reaction
Wittig Reaction
Horner–Wadsworth–Emmons Reaction
Asymmetric Alkylation
Olefin Cross-Metathesis
Cross-Dehydrogenative Coupling
Reformatsky Reaction
Cascade Reactions
Arylaminomethylation
Naphthopyran Synthesis
Carbon–Nitrogen Bond-Formation Reactions
1,2-Dione/Diamine Condensation
Synthesis of Imines
Synthesis of (Thio)semicarbazones
Synthesis of Oximes
Synthesis of Hydrazones
Synthesis of Azines
Amide and Thioamide Bond Formation
Synthesis of Nitrones
Synthesis of Enamines and Enamine Ketones
Alkylation of Nitrogen
Synthesis of Biguanides and Guanidines
Additions to Double and Triple Bonds
Substitution Reactions
N-Arylation of Amines
Biginelli Reaction
Nitroso Bond Formation/Dissociation
Carbon—Oxygen and Other Bond-Formation Reactions
C—O Bond Formation Reactions
Sulfur Bond Formation Reactions
Halogen Bond Formation Reactions
Phosphorus Bond Formation Reactions
Boron Bond Formation Reactions
Silicon Bond Formation Reactions
Bismuth Bond Formation Reactions
C—H Bond Formation: Hydrogenation
Multistep Mechanochemical Reaction
Cycloaddition Reactions
Diels–Alder Reaction
1,3-Dipolar Cycloadditions
Oxidations and Reductions
Oxidations
Reductions
Applications of Ball Milling in Nanocarbon Material Synthesis
Functionalization of Fullerenes
Functionalization of Single-Walled Carbon Nanotubes
Functionalization of Graphenes
Applications of Ball Milling in Supramolecular Chemistry
Rotaxanes
Complexation of Fullerenes
Experiments for Introduction of Mechanochemistry in the Undergraduate Curriculum
Green Chemistry at the University Level
Selected Experiments
Author Index
Subject Index
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