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Morales-Morales D. (ed.) Pincer Compounds: Chemistry and Applications

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Morales-Morales D. (ed.) Pincer Compounds: Chemistry and Applications
Elsevier Inc., 2018. — 746 p. — ISBN: 978-0-12-812931-9
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area.
Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications.
Contents
Chiral Pincer Complexes for Asymmetric Reactions
Well-defined Iron and Manganese Pincer Catalysts
The Pincer Complexes of Group 1315 Elements: Recent Developments
Reduction of CO2 Mediated or Catalyzed by Pincer Complexes
Mechanistic Insights and Computational Prediction of Base Metal Pincer Complexes for Catalytic Hydrogenation and Dehydrogenation
Reactions
Hydrogenation and Dehydrogenation Reactions Catalyzed by Iron Pincer Compounds
Actinide Pincer Chemistry: A New Frontier
Complexes of NHC-Based CEC Pincer Ligands: Structural Diversity and Applications
Transition Metal Pincer Complexes With Chiral Imidazoline Donor(s): Synthesis and Asymmetric Catalysis
Chiral NCN Pincer-Type Catalysts Having Bis(imidazoline)s
Transition Metal Pincer Complexes with a Central sp3-Hybridized Carbon Atom
CCC-NHC Pincer Complexes: Synthesis, Applications, and Catalysis
Metal Pincer Catalysts in Aqueous Media: Approaches With Water as Solvent, Reagent, and Molecular Hydrogen Storage
Pincers Based on Dicarboxamide and Dithiocarboxamide Functional Groups
Pincer Complexes of Iron and Their Application in Catalysis
Osmium Complexes With POP Pincer Ligands
Pincer Carbenoid Complexes With Late Transition Metals: Synthesis, Electronic Structure, and Reactivity
Pincer Iridium and Ruthenium Complexes for Alkane Dehydrogenation
Silicon-Based Pincers: Trans Influence and Functionality
Transition Metal Complexes With Anionic Sulfur-Based Pincer Ligands
Metalation and Transmetalation Chemistry of Pyridine- and Aryl-Linked Bis-NHC Pincer Ligands
Unsymmetrical Pincer Palladacycles Synthesis and Reactivity
Benzene-Derived Organometallic Pincer Compounds Bearing Six-Membered Metallacycles and Up
Chemistry of Mn and Co Pincer Compounds
Selective Deuteration of Organic Compounds Catalyzed by Ruthenium Pincer Complexes
σ-Organometallic Chemistry With 2,6-Bis (imino)pyridine Ligands: New Pathways to Innovative Pincer Architectures
Use of Pincer Compounds as Metal-Based Receptors for Chemosensing of Relevant Analytes
Advances in the Design and Application of Redox-Active and Reactive Pincer Ligands for Substrate Activation and Homogeneous Catalysis
The Chemistry of Bisphosphomide and 1,2-Phenylenediamine Based PBP Pincer Transition Metal Complexes and Catalytic Applications
Ligand-Introduction Synthesis of NCNPincer Complexes and their Chemical Properties
Pincer Complexes of Gold: An Overview of Synthesis, Reactivity, Photoluminescence, and Biological Applications
Semirigid Pincer-Like SiPSi Ligands: Classical Versus Nonclassical Coordination Modes at Ru, Rh, Ir, and Pt
Conclusions and Personal Comment
Index
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