3rd Edition. — Oxford University Press, 2017. — 1440 p. — ISBN 9780198733805.Chemistry is widely considered to be the central science: it encompasses concepts from which other branches of science are developed. Yet, for many students entering university, gaining a firm grounding in chemistry is a real challenge. Chemistry³ responds to this challenge, providing students with a full understanding of the fundamental principles of chemistry on which to build later studies. Uniquely amongst the introductory chemistry texts currently available, Chemistry³ is written by a team of chemists to give equal coverage of organic, inorganic and physical chemistry - coverage that is uniformly authoritative. The approach to organic chemistry is mechanistic, rather than the old-fashioned 'functional group' approach, to help students achieve a fuller understanding of the underlying principles. Chemistry³ tackles head-on two issues pervading chemistry education: students' mathematical skills, and their ability to see the subject as a single, unified discipline. Instead of avoiding the maths, Chemistry³ provides structured support, in the form of careful explanations, reminders of key mathematical concepts, step-by-step calculations in worked examples, and a Maths Toolkit, to help students get to grips with the essential mathematical element of chemistry. Frequent cross-references highlight the connections between each strand of chemistry and explain the relationship between the topics, so students can develop an understanding of the subject as a whole. Содержание Fundamentals The language of organic chemistry Atomic structure and properties Diatomic molecules Polyatomic molecules Solids Acids and bases Gases Reaction kinetics Molecular spectroscopy Analytical chemistry Molecular characterization Energy and thermochemistry Entropy and Gibbs energy Chemical equilibrium Electrochemistry Phase equilibrium and solutions Isomerism and stereochemistry Organic reaction mechanisms Substitution and elimination reactions Electrophilic addition and pericyclic reactions Electrophilic substitution reactions Nucleophilic addition and αsubstitution reactions nucleophilic acyl substitution and αsubstitution reactions Hydrogen sBlock chemistry pBlock chemistry dBlock chemistry Maths toolkit Appendixes Abbreviations and symbols for quantities and units Representing reactions Preparation and reactions of alcohols and amines Organic oxidation and reduction reactions Properties of the elements Electronic configurations of the elements and some important ions Thermodynamic data for organic and inorganic compounds Ionic atomic and van der Waals radii for selected elements Acidity constants Bond lengths and bond enthalpies The electromagnetic spectrum
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