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Davis B., Occelli M. (eds.) Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis

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Davis B., Occelli M. (eds.) Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis
CRC Press. Taylor & Francis Group, 2009. — 424 p. — ISBN: 978-1-4200-6256-4.
The book focuses on three main themes: catalyst preparation and activation, reaction mechanism, and process-related topics. A panel of expert contributors discusses synthesis of catalysts, carbon nanomaterials, nitric oxide calcinations, the influence of carbon, catalytic performance issues, chelating agents, and Cu and alkali promoters. They also explore Co/silica catalysts, thermodynamic control, the Two Alpha model, co-feeding experiments, internal diffusion limitations, Fe-LTFT selectivity, and the effect of co-fed water. Lastly, the book examines cross-flow filtration, kinetic studies, reduction of CO2 emissions, syncrude, and low-temperature water-gas shift.
The themes explored in the book demonstrate that while the Fischer-Tropsch synthesis (FTS) has advanced in maturity, many issues remain concerning the preparation of increasingly active catalysts and the method of activation to attain the maximum catalytic activity and catalyst life. The book includes coverage of the structural features, their changes, and the application of increasingly sophisticated characterization techniques, shedding light on the reaction mechanism and providing a glimpse into the processes and reaction rates under realistic commercial process conditions.
Contents
Preface
The Editors
Contributors
Synthesis of High Surface Area Cobalt-on-Alumina Catalysts by Modification with Organic Compounds
Carbon Nanomaterials as Supports for Fischer-Tropsch Catalysts
Effect of a Novel Nitric Oxide Calcination on the Catalytic Behavior of Silica-Supported Cobalt Catalysts during Fischer-Tropsch Synthesis, and Impact on Performance Parameters
The Formation and Influence of Carbon on Cobalt-Based Fischer-Tropsch Synthesis Catalysts: An Integrated Review
Catalytic Performance of Ru/Al2O3 and Ru/Mn/Al2O3 for Fischer-Tropsch Synthesis
Preparation of Highly Active Co/SiO2 Catalyst with Chelating Agents for Fischer-Tropsch Synthesis: Role of Chelating Agents
Fischer-Tropsch Synthesis: Temperature-Programmed EXAFS/XANES Characterization of the Impact of Cu and Alkali Promoters to Iron-Based Catalysts on the Carbide Formation Rate
Characterization of Co/Silica Catalysts Prepared by a Novel NO Calcination Method
Fischer-Tropsch Synthesis and Hydroformylation on Cobalt Catalysts: The Thermodynamic Control
The Value of a Two Alpha Model in the Elucidation of a Full Product Spectrum for Fe-LTFT
Studies on the Reaction Mechanism of the Fischer-Tropsch Synthesis: Co-Feeding Experiments and the Promoter Effect of Alkali
Modeling of Internal Diffusion Limitations in a Fischer-Tropsch Catalyst
Fe-LTFT Selectivity: A Sasol Perspective
Fischer-Tropsch Synthesis: Comparison of the Effect of Co-Fed Water on the Catalytic Performance of Co Catalysts Supported on Wide-Pore and Narrow-Pore Alumina
Fischer-Tropsch Synthesis: A Continuous Process for Separation of Wax from Iron Nano-Catalyst Particles by Using Cross-Flow Filtration
Detailed Kinetic Study and Modeling of the Fischer-Tropsch Synthesis over a State-of-the-Art Cobalt-Based Catalyst
Reduction of CO2 Emissions from CTL Processes: Use of a Novel FT-Based Chemistry
Refining Fischer-Tropsch Syncrude: Perspectives on Lessons from the Past
Low-Temperature Water-Gas Shift: Assessing Formates as Potential Intermediates over Pt/ZrO2 and Na-Doped Pt/ZrO2
Catalysts Employing the SSITKA-DRIFTS Technique
Index
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