Voytenko L.V, Kosmatiy V.E., Kopilevich V.A. Analytical Chemistry

Manual for Bachelors students, Kyiv,Publishing Center Nau, 2007. — 199 p.It was expounded the main theoretical notions of Analytical chemistry. Manual includes Laboratory training and practice problems for students’ self-control.The nature of analytical chemistry
What information does chemical analysis provide?
Analytical techniques
Semimicro Techniques
Analytical Techniques
Analytical Glassware
Laboratory glassware cleaning procedures
Analytical purity of chemicals
Calculating Concentration: Units & Dilutions
Qualitative analysis
General ideas
Qualitative analysis of cations
The first group of cations
Characteristic reactions of ammonia cations NH₄⁺
Characteristic reactions of Potassium cations K⁺
Characteristic reactions of Sodium cations Na⁺
The third group of cations
Characteristic reactions of Copper cations Cu₂⁺
Characteristic reactions of Zinc cations Zn₂⁺
Characteristic reactions of Cobalt cations Co₂⁺
Characteristic reactions of Nickel cations Ni₂⁺
The second group of cations
Characteristic reactions of Magnesium cations Mg²⁺
Characteristic reactions of Calcium cations Ca²⁺
Characteristic reactions of Strontium cations Sr²⁺
Characteristic reactions of Manganese cations Mn²⁺
Characteristic reactions of Ferrous cations Fe²⁺
Characteristic reactions of Ferric cations Fe³⁺
Characteristic reactions of Aluminium cations Al³⁺
The fourth group of cations
Characteristic reactions of Silver cations Ag⁺
Characteristic reactions of Lead cations Pb²⁺
Qualitative analysis of anions
The first group of anions
Characteristic reactions of Sulfate anions SO₄^2-
Characteristic reactions of Sulfite anions SO₃^2-
Characteristic reactions of Carbonate anions CO₃^2-
Characteristic reactions of Phosphate anions PO₄^3-
Characteristic reactions of Borate anions B₄O₇^2- (BO₂^-)
Characteristic reactions of Molybdate anions MoO₄^2-
Characteristic reactions of Silicate anions SiO₃^2-
The second group of anions
Characteristic reactions of Chloride anions Cl^-
Characteristic reactions of Bromide anions Br^-
Characteristic reactions of Iodide anions I^-
The third group of anions
Characteristic reactions of Nitrite anions NO₂^-
Characteristic reactions of Nitrate anions NO₃^-
Characteristic reactions of Acetate anions CH₃COO^-
Analysis of mixture of cations of I-IV analytical groups
Order of fractional and systematic analysis of cations’ mixture of I-IV analytical groups
Fractional analysis
Systematic analysis
Analysis of unknown substance
Identifying a Simple Salt by logistics way
Odentifying a Simple Salt by step-by-step way
Qualitative analysis of insoluble substances and solutions
Quantitative analysis
Chemical equilibrium in heterogeneous systems
Molar solubility and solubility
Predicting precipitation reactions
The common ion effect and solubility
Gravimetry
Physical Gravimetry
Laboratory work - Physical gravimetry. Determination of water in Hydrated Barium Chloride
Precipitative Gravimetry
Laboratory work - Precipitate gravimetry. Determination of Sulfates content in water or Barium content in Hydrated Barium Chloride
Fundamentals of Titrimetry
Classification of volumetric methods
Steps in a Titration
Neutralization method
Laboratory work. Determination of normality of alkali solution
Oxidation-reduction (Redox) Titration (Redoxmetry)
General Principles of Redoxmetry
Quantitative Characteristic of Direction and Completeness of Passing of Oxidation-Reduction Reaction
Laboratory work. Determination of Iron (II) content in More’s salt
Complexonometry (Chelatometry)
Laboratory work. Determination of Total Water Hardness
Аppendixes