Burgot J.-L. Ionic Equilibria in Analytical Chemistry

Springer Science+Business Media, 2012. - 770 p. - ISBN: 1441983813.This book of general analytical chemistry – as opposed to instrumental analysis or separation methods – in aqueous solutions is focuses on fundamentals, which is an area too often overlooked in the literature. Explanations abound of the chemical and physical principles of different operations of chemical analysis in aqueous solutions. Once these principle are firmly established, numerous examples of applications are also given.General Considerations
Solvents—Composition of Solutions
Thermodynamics and Equilibrium
Activities and Activity CoefficientsAcids and Bases Equilibria—Analytical Applications
Definitions of Acids and Bases: Strength of Acids and Bases
Calculations of pH Values in Aqueous Solutions
Buffer Solutions
Some General Points Concerning Titrations
Neutralization or Acid-Base Indicators
Acid–Base Titration Curves
Acid–Base Titrations: Further Theoretical Studies
Acid–Base Reactions and Chemical AnalysisRedox Phenomena and Analytical Applications
Generalities on Oxidation-Reduction
Redox Reactions and Electrochemical Cells
Predicting Redox Reactions
Predicting Redox Reactions by Graphical Means
Calculating Equilibrium Potentials of Solutions Containing Several Redox Couples
A Study of Some Redox Titration Curves
Oxidoreductimetry: Direct and Indirect Iodometries
Iodometry in Alkaline Medium, Iodatometry, Periodimetry, and Bromometry
Oxidizations with Permanganate, Dichromate, and Ceric Ions Some Titration Methods Involving a Reduction Reaction
Some Applications of Redox Reactions in Qualitative AnalysisComplexation Reactions—Analytical Applications
General Definitions Concerning Complexes Rules of Nomenclature and Writing
Some Elements Concerning the Chemistry of Complexes
Stability of Complexes: Some Elements Concerning the Kinetics of Their Formation
Superimposition of Varied Equilibria to Complexation Equilibria
Conditional Stability Constants
Complexometry I: Mercurimetry (Votocek–Dubsky’s Method)
Complexometry II: Titrations with EDTA
Complexometry III: Metal Cation Indicators and Types of EDTA Titrations
Applications of the Formation of Complexes in Inorganic AnalysisPrecipitation Phenomena—Analytical Applications
Applications of the Formation of Complexes in Organic Analysis
Intrinsic, Ionic, and Total Solubilities; Solubility Product and Precipitation
Dependence of the Solubility on the Solution’s Ionic Strength and on the Presence of Common Ions: Superimposition of Several Precipitation Equilibria
Solubility and pH
Precipitation and Complexation
Theoretical Study of Some Precipitation Titration Curves
Titrimetric Methods Involving a Precipitation
Gravimetry by Precipitation
Some Applications of the Precipitation Phenomenon in Inorganic and Organic Qualitative and Quantitative Analysis